Publications

地球温暖化や化石燃料の枯渇等の問題から、新エネルギーの早期普及と低環境負荷技術の確立が強く望まれています。
当講座では、バッテリー・燃料電池・ガスセンサー・リアクターなどの電気化学デバイスを高効率化するための「マテリアルとシステムの設計」を行っています。最近では、カーボンニュートラルなバイオマス資源に着目し、低環境負荷でエネルギを取り出す研究を行っています。

2021

Hibino T, Kobayashi K, Teranishi S, Hitomi T.
Solid oxide fuel cell using municipal solid waste directly as fuel: biomass, resin, plastic, and food waste
ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9(8):3124-3136 MAR 2021
Hibino T, Kobayashi K, Hitomi T.
Biomass solid oxide fuel cell using solid weed waste as fuel
ELECTROCHIMICA ACTA 388: 138681 AUG 2021
Hibino T, Kobayashi K, Hitomi T.
Solid oxide fuel cell using plastic waste directly as fuel
CHEMISTRY LETTERS 50(10): 1729-1732 OCT 2021

2020

Hori T, Kobayashi K, Teranishi S, Nagao M, Hibino T.
Fuel cell and electrolyzer using plastic waste directly as fuel
WASTE MANAGEMENT 102: 30-39 JAN 2020

2019

Hori T, Ma Q, Kobayashi K, Nagao M,Teranishi S, Hibino T.
Electrolysis of humidified methane to hydrogen and carbon dioxide at low temperatures and voltages
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 44: 2454-2460 JAN 2019

2018

Ito M, Hori T, Teranishi S, Nagao M, Hibino T.
Intermediate-temperature electrolysis of energy grass Miscanthus sinensis for sustainable hydrogen production
SCIENTIFIC REPORTS 8: 16186 NOV 2018
Hibino T, Kobayashi K, Ito M, Ma Q, Nagao M, Fukui M, Teranishi S.
Efficient hydrogen production by direct electrolysis of waste biomass at intermediate temperatures
ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6: 9360-9368 MAY 2018
Hibino T, Kobayashi K, Nagao M, Teranishi S.
Direct electrolysis of waste newspaper for sustainable hydrogen production: an oxygen-functionalized porous carbon anode
APPLED CATALYSIS B: ENVIRONMENTAL 231: 191-199 MAR 2018

2017

Hibino T, Kobayashi K, Nagao M, Teranishi S.
Hydrogen production by direct Lignin electrolysis at intermediate temperatures
CHEMELECTROCHEM 4 (12): 3032-3036 DEC 2017
Hibino T, Kobayashi K, Lv P, Nagao M, Teranishi S.
High performance anode for direct cellulosic biomass fuel cells operating at intermediate temperatures?
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 90 (9): 1017-1026 SEP 2017
Nagao M, Kobayashi K, Lv P, Teranishi S, Hibino T.
An intermediate-temperature biomass fuel cell using wood sawdust and pulp directly as fuel
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 164 (6): F557-F563 JUN 2017

2016

Hibino T, Kobayashi K, Nagao M.
Kinetically driven switching and memory phenomena at the interface between a proton-conductive electrolyte and a titanium electrode
SCIENTIFIC REPORTS 6 : 31691 AUG 2016
Hibino T, Kobayashi K, Nagao M, et al.
Design of a rechargeable fuel-cell battery with enhanced performance and cyclability
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 163 (7): A1420-A1428 JUL 2016
Nagao M, Kobayashi K, Yamamoto Y, et al.
Rechargeable metal-air proton-exchange membrane batteries for renewable energy storage
CHEMELECTROCHEM 3 (2): 247-255 FEB 2016
Kobayashi K, Nagao M, Hibino T.
A rechargeable Tin-air PEM battery using SnSO4 as an anode-active material
CHEMISTRY LETTERS 45 (2): 161-163 FEB 2016

2015

Kobayashi K, Nagao M, Yamamoto Y, et al.
Rechargeable REM fuel-cell batteries using porous carbon modified with carbonyl groups as anode materials
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 162 (8): F868-F877 AUG 2015
Viet-Ha T, Yatabe T, Matsumoto T, et al.
An IrSi oxide film as a highly active water-oxidation catalyst in acidic media
CHEMICAL COMMUNICATIONS 51: 12589-12592 JUN 2015
Nagao M, Kobayashi K, Hibino T.
A direct urine fuel cell operated at intermediate temperatures
CHEMISTRY LETTERS 44 (3): 363-365 MAR 2015
Nagao M, Kobayashi K, Yamamoto Y, et al.
Rechargeable REM fuel-cell batteries using quinones as hydrogen carriers
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 162 (4): F410-F418 APR 2015
Hibino T, Kobayashi K, Nagao M, et al.
High-temperature supercapacitor with a proton-conducting metal pyrophosphate electrolyte
SCIENTIFIC REPORTS 5: 7903 JAN 2015

2014

Matsumoto T, Eguchi S, Nakai H, et al.
[NiFe] Hydrogenase from citrobacter sp S-77 surpasses platinum as an electrode for H-2 oxidation reaction
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53 : 8895-8898 AUG 2014
Heo P, Shen YB, Kojima K, et al.
Fe0.4Ta0.5P2O7-based composite membrane for high-temperature, low-humidity proton exchange membrane fuel cells
ELECTROCHIMICA ACTA 128: 287-291 MAY 2014

2013

Hibino T, Kobayashi K, Heo P.
Oxygen reduction reaction over nitrogen-doped graphene oxide cathodes in acid and alkaline fuel cells at intermediate temperatures
ELECTROCHIMICA ACTA 112: 82-89 DEC 2013
Hibino T, Kobayashi K, .Nagao M.
An all-solid-state rechargeable aluminum-air battery with a hydroxide ion-conducting Sb(V)-doped SnP2O7 electrolyte
JOURNAL OF MATERIALS CHEMISTRY A 1 (47): 14844-14848 DEC 2013
Matsumoto T, Kim K, Nakai H, et al.
Organometallic catalysts for use in a fuel cell
CHEMCATCHEM 5 (6): 1368-1373 JUN 2013
Hibino T, Kobayashi K.
Intermediate-temperature alkaline fuel cells with non-platinum electrodes
JOURNAL OF MATERIALS CHEMISTRY A 1 (24): 7019-7022 MAY 2013
Hibino T, Kobayashi K.
An intermediate-temperature alkaline fuel cell using an Sn0.92Sb0.08P2O7-based hydroxide-ion-conducting electrolyte and electrodes
JOURNAL OF MATERIALS CHEMISTRY A 1 (4): 1134-1140 JAN 2013

2012

Shen YB, Heo P, Pak C, et al.
Intermediate-temperature, non-humidified proton exchange membrane fuel cell with a highly proton-conducting Fe0.4Ta0.5P2O7 electrolyte
ELECTROCHEMISTRY COMMUNICATIONS 24: 82-84 OCT 2012

2011

Jin YC, Nishida M, Kanematsu W, et al.
An H3PO4-doped polybenzimidazole/Sn0.95Al0.05P2O7 composite membrane for high-temperature proton exchange membrane fuel cells
JOURNAL OF POWER SOURCES 196 (15): 6042-6047 AUG 2011
Dong X, Takahashi M, Nagao M, et al.
Compact bipolar plate-free direct methanol fuel cell stacks
CHEMICAL COMMUNICATIONS 47 (18): 5292-5294 2011
Jin YC, Okada M, Hibino T
A comparative study of Pt/C cathodes in Sn0.9In0.1P2O7 and H3PO4 ionomers for high-temperature proton exchange membrane fuel cells
JOURNAL OF POWER SOURCES 196 (11): 4905-4910 JUN 2011

2010

Nagao M, Takahashi M, Hibino T
Separator-free fuel cell stacks operating in a mixture of hydrogen and air
ENERGY & ENVIRONMENTAL SCIENCE 3 (12): 1934-1940 DEC 2010
Harada T, Jin YC, Heo P, et al.
Cathodes for high-temperature PEM fuel cells based on a Si0.97Al0.03C promoter and a Sn0.95In0.05P2O7 ionomer
FUEL CELLS 10 (5): 798-803 OCT 2010
Jin YC, Lee B, Hibino T
Development and application of SnP2O7-based proton conductors to intermediate-temperature fuel cells
JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 53 (1): 12-23 JAN 2010

2009

Heo P, Harada T,Hibino T
Nanostructured Pt-Sn1-xInxP2O7 cathodes for high-temperature proton exchange membrane fuel cells
ELECTROCHEMICAL AND SOLID STATE LETTERS 12 (1): B1-B4 JAN 2009

2008

Nagao M, Yano M, Okamoto K, et al.
A single-chamber SOFC stack : energy recovery from engine exhaust
FUEL CELLS 5 : 322-329 OCT 2008
Heo P, Ito K, Tomita A, et al.
A proton-conducting fuel cell operating with hydrocarbon fuels
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 47 : 7841-7844 OCT 2008
Heo P, Shibata H, Nagao M, et al.
Pt-free intermediate-temperature fuel cells
SOLID STATE IONICS 179 : 1446-1449 SEP 2008
Yano M, Nagao M, Okamoto K, et al.
A single-chamber SOFC stack operating in engine exhaust
ELECTROCHEMICAL AND SOLID STATE LETTERS 11 (3): B29-B33 MAR 2008
Heo P, Nagao M, Sano M, et al.
Direct dimethyl ether fuel cells at intermediate temperatures
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 155 (1): B92-B95 JAN 2008

2007

Yano M, Kawai T, Okamoto K, et al.
Single-chamber SOFCs using dimethyl ether and ethanol
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 154 (8): B865-B870 AUG 2007
Yano M , Tomita A, Sano M, et al.
Recent advances in single-chamber solid oxide fuel cells:A review
SOLID STATE IONICS 177 : 3351-3359 JAN 2007
Heo P, Nagao M, Sano M, et al.
A high-performance Mo2C-ZrO2 anode catalyst for intermediate-temperature fuel cells
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 154 (1): B53-B56 JAN 2007

2006

Tomita A, Tunekawa K, Hibino T, et al.
Chemical and redox stabilities of a solid oxide fuel cell with BaCe0.8Y0.2O3-α functioning as an electrolyte and as an anode
SOLID STATE IONICS 177 : 2951-2956 NOV 2006
Tomita A, Teranishi S, Nagao M, et al.
Comparative performance of anode-supported SOFCs using a thin Ce0.9Gd0.1O1.95 electrolyte with an incorporated BaCe0.8Y0.2O3-α layer in hydrogen and methane
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 153 (6): A956-A960 JUN 2006
Heo P, Shibata H, Nagao M, et al.
Performance of an intermediate-temperature fuel cell using a proton-conducting Sn0.9In0.1P2O7 electrolyte
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 153 (5): A897-A901 MAY 2006

2005

Tomita A, Hibino T, Sano M
Surface modification of a doped BaCeO3 to function as an electrolyte and as an anode for SOFCs
ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (7): A333-A336 JUL 2005
Hirabayashi D, Tomita A, Teranishi S, et al.
Improvement of a reduction-resistant Ce0.8Sm0.2O1.9 electrolyte by optimizing a thin BaCe1-xSmxO3＜ｿ layer for intermediate-temperature SOFCs
SOLID STATE IONICS 176 (9-10): 881-887 MAR 15 2005
Tomita A, Hirabayashi D, Hibino T , et al.
Single-chamber SOFCs with a Ce0.9Gd0.1O1.95 electrolyte film for low-temperature operation
ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (1): A63-A65 JAN 2005

2004

Hirabayashi D, Tomita A, Brito ME, et al.
Solid oxide fuel cells operating without using an anode material
SOLID STATE IONICS 168 (1-2): 23-29 MAR 15 2004
Hirabayashi D, Hashimoto A, Hibino T, et al.
Design of a reduction-resistant Ce0.8Sm0.2O1.9 electrolyte through growth of a thin BaCe1-xSmxO3-αlayer over electrolyte surface
ELECTROCHEMICAL AND SOLID STATE LETTERS 7 (10): A318-A320 OCT 2004
Hirabayashi D, Hashimoto A, Hibino T, et al.
Bi-based oxide anodes for direct hydrocarbon SOFCs at intermediate temperatures
ELECTROCHEMICAL AND SOLID STATE LETTERS 7 (5): A108-A110 MAY 2004
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