Publications

地球温暖化や化石燃料の枯渇等の問題から、新エネルギーの早期普及と低環境負荷技術の確立が強く望まれています。
当講座では、バッテリー・燃料電池・ガスセンサー・リアクターなどの電気化学デバイスを高効率化するための「マテリアルとシステムの設計」を行っています。最近では、カーボンニュートラルなバイオマス資源に着目し、低環境負荷でエネルギを取り出す研究を行っています。

2015

Hibino T, Kobayashi K, Nagao M, et.al
High-temperature supercapacitor with a proton-conducting metal pyrophosphate electrolyte
SCIENTIFIC REPORTS 5 : 7903 JAN 2015
Times Cited: 26

2013

Hibino T, Kobayashi K, Heo P
Oxygen reduction reaction over nitrogen-doped graphene oxide cathodes in acid and alkaline fuel cells at intermediate temperatures
ELECTROCHIMICA ACTA 112 : 82-89 DEC 2013
Times Cited: 25
Matsumoto T, Kim K, Nakai H, et al.
Organometallic Catalysts for Use in a Fuel Cell
CHEMCATCHEM 5 (6) : 1368-1373 JUN 2013
Times Cited: 20

2012

Sato Y, Shen YB, Nishida M, et al.
Proton conduction in non-doped and accepter-doped metal pyrophosphate (MP2O7) composite ceramics at intermediate temperatures
JOURNAL OF MATERIALS CHEMISTRY 22 (9): 3973-3981 MAR 2012
Times Cited: 33

2011

Jin YC, Nishida M, Kanematsu W, et al.
An H3PO4-doped polybenzimidazole/Sn0.95Al0.05P2O7 composite membrane for high-temperature proton exchange membrane fuel cells
JOURNAL OF POWER SOURCES 196 (15): 6042-6047 AUG 2011
Times Cited: 21
Shen YB, Nishida M, Kanematsu W, et al.
Synthesis and characterization of dense SnP2O7-SnO2 composite ceramics as intermediate-temperature proton conductors
JOURNAL OF MATERIALS CHEMISTRY 21 (3): 663-670 JAN 2011
Times Cited: 31

2010

Jin YC, Shen YB, Hibino T
Proton conduction in metal pyrophosphates (MP2O7) at intermediate temperatures
JOURNAL OF MATERIALS CHEMISTRY 20 (30): 6214-6217 AUG 2010
Times Cited: 67
Jin YC, Fujiwara K, Hibino T
High temperature, low humidity proton exchange membrane based on an inorganic-organic hybrid structure
ELECTROCHEMICAL AND SOLID STATE LETTERS 13 (2): B8-B10 FEB 2010
Times Cited: 22

2009

Genzaki K, Heo P, Sano M, et al.
Proton conductivity and solid acidity of Mg-, In-, and Al-doped SnP2O7
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 156 (7): B806-B810 JUL 2009
Times Cited: 41
Teranishi S, Kondo K, Tsuge A, et al.
Selective electrochemical oxidation of carbon by active oxygen for potential application as a sensor for diesel particulates
SENSORS AND ACTUATORS B-CHEMICAL 140 (1): 170-175 JUN 2009
Times Cited: 20

2008

Heo P, Ito K, Tomita A, et al.
A proton-conducting fuel cell operating with hydrocarbon fuels
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 47 : 7841-7844 OCT 2008
Times Cited: 45
Nagao M, Yano M, Okamoto K, et al.
A Single-chamber SOFC stack: Energy recovery from engine exhaust
FUEL CELLS 8 (5): 322-329 OCT 2008
Times Cited: 24
Heo P, Kajiyama N, Kobayashi K, et al.
Proton conduction in Sn0.95Al0.05P2O7-PBI-PTFE composite membrane
ELECTROCHEMICAL AND SOLID STATE LETTERS 11 (6): B91-B95 JUN 2008
Times Cited: 30
Yano M, Nagao M, Okamoto K, et al.
A Single-chamber SOFC stack operating in engine exhaust
ELECTROCHEMICAL AND SOLID STATE LETTERS 11 (3): B29-B33 MAR 2008
Times Cited: 32
Tomita A, Nakajima J, Hibino T
Direct oxidation of methane to methanol at low temperature and pressure in an electrochemical fuel cell
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 47 (8): 1462-1464 JAN 2008
Times Cited: 27

2007

Tomita A, Kajiyama N, Kamiya T, et al.
Intermediate-temperature proton conduction in Al3+-doped SnP2O7
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 154 (12): B1265-B1269 DEC 2007
Times Cited: 76
Tomita A, Namekata Y, Nagao M, et al.
Room-temperature hydrogen sensors based on an In3+-doped SnP2O7 proton conductor
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 154 (5): J172-J176 MAY 2007
Times Cited: 24
Tomita A, Yoshii T, Teranishi S, et al.
Selective catalytic reduction of NOx by H2 using proton conductors as catalyst supports
JOURNAL OF CATALYSIS 247 (2): 137-144 APR 25 2007
Times Cited: 41
Yano M , Tomita A, Sano M, et al.
Recent advances in single-chamber solid oxide fuel cells:A review
SOLID STATE IONICS 177 : 3351-3359 JAN 2007
Times Cited: 181
Heo P, Nagao M, Kamiya T, et al.
Sn0.9In0.1P2O7-based organic/inorganic composite membranes application to intermediate-temperature fuel cells
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 154 (1): B63-B67 JAN 2007
Times Cited: 31
Heo P, Nagao M, Sano M, et al.
A high-performance Mo2C-ZrO2 anode catalyst for intermediate-temperature fuel cells
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 154 (1): B53-B56 JAN 2007
Times Cited: 23

2006

Tomita A, Tsunekawa K, Hibino T, et al.
Chemical and redox stabilities of a solid oxide fuel cell with BaCe0.8Y0.2O3-alpha functioning as an electrolyte and as an anode
SOLID STATE IONICS 177 (33-34): 2951-2956 NOV 15 2006
Times Cited: 26
Nagao M, Kamiya T, Heo P, et al.
Proton conduction in In3+-doped SnP2O7 at intermediate temperatures
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 153 (8): A1604-A1609 AUG 2006
Times Cited: 120
Nagao M, Namekata Y, Hibino T, et al.
Intermediate-temperature NOx sensor based on an In3+-doped SnP2O7 proton conductor
ELECTROCHEMICAL AND SOLID STATE LETTERS 9 (6): H48-H51 JUN 2006
Times Cited: 21
Tomita A, Teranishi S, Nagao M, et al.
Comparative performance of anode-supported SOFCs using a thin Ce0.9Gd0.1O1.95 electrolyte with an incorporated BaCe0.8Y0.2O3-α layer in hydrogen and methane
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 153 (6): A956-A960 JUN 2006
Times Cited: 40
Heo P, Shibata H, Nagao M, et al.
Performance of an intermediate-temperature fuel cell using a proton-conducting Sn0.9In0.1P2O7 electrolyte
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 153 (5): A897-A901 MAY 2006
Times Cited: 39
Nagao M, Takeuchi A, Heo P, et al.
A proton-conducting In3+-doped SnP2O7 electrolyte for intermediate-temperature fuel cells
ELECTROCHEMICAL AND SOLID STATE LETTERS 9 (3): A105-A109 MAR 2006
Times Cited: 125
Nagao M, Yoshii T, Hibino T, et al.
Electrochemical reduction of NOx at intermediate temperatures using a proton-conducting In3+-doped SnP2O7 electrolyte
ELECTRCHEMICAL AND SOLID STATE LETTERS 9 (2):J1-J4 FEB 2006
Times Cited: 23

2005

Hirabayashi D, Tomita A, Teranishi S, et al.
Improvement of a reduction-resistant Ce0.8Sm0.2O1.9 electrolyte by optimizing a thin BaCe1-xSmxO3-α layer for intermediate-temperature SOFCs
SOLID STATE IONICS 176 (9-10): 881-887 MAR 15 2005
Times Cited: 71
Tomita A, Hirabayashi D, Hibino T , et al.
Single-chamber SOFCs with a Ce0.9Gd0.1O1.95 electrolyte film for low-temperature operation
ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (1): A63-A65 JAN 2005
Times Cited: 35

2004

Hirabayashi D, Hashimoto A, Hibino T , et al.
Design of a reduction-resistant Ce0.8Sm0.2O1.9 electrolyte through growth of a thin BaCe1-xSmxO3-αlayer over electrolyte surface
ELECTROCHEMICAL AND SOLID STATE LETTERS 7 (10): A318-A320 OCT 2004
Times Cited: 32
Takahashi K, Saitoh M, Asakura N, et al.
Electrochemical properties of lithium manganese oxides with different surface areas for lithium ion batteries
JOURNAL OF POWER SOURCES 136 (1): 115-121 SEP 2004
Times Cited: 22
Tomita A, Hibino T, Suzuki M, et al.
Proton conduction at the surface of Y-doped BaCeO3 and its application to an air/fuel sensor
JOURNAL OF MATERIALS SCIENCE 39 (7): 2493-2497 APR 2004
Times Cited: 23

2003

Hibino T, Hashimoto A, Yano M, et al.
Ru-catalyzed anode materials for direct hydrocarbon SOFCs
ELECTROCHIMICA ACTA 48 (17): 2531-2537 JUL 15 2003
Times Cited: 79

2002

Hibino T, Hashimoto A, Suzuki M, et al.
A solid oxide fuel cell using Y-doped BaCeO3 with Pd-loaded FeO anode and Ba0.5Pr0.5CoO3 cathode at low temperatures
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 149 (11): A1503-A1508 NOV 2002
Times Cited: 193
Hibino T, Hashimoto A, Asano K, et al.
An intermediate-temperature solid oxide fuel cell providing higher performance with hydrocarbons than with hydrogen
ELECTROCHEMICAL AND SOLID STATE LETTERS 5 (11): A242-A244 NOV 2002
Times Cited: 109
Hibino T, Hashimoto A, Suzuki M, et al.
A solid oxide fuel cell with a novel geometry that eliminates the need for preparing a thin electrolyte film
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 149 (2): A195-A200 FEB 2002
Times Cited: 43
Hibino T, Hashimoto A, Yano M, et al.
High performance anodes for SOFCs operating in methane-air mixture at reduced temperatures
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 149 (2): A133-A136 FEB 2002
Times Cited: 140

2001

Hashimoto A, Hibino T, Mori K, et al.
High-temperature hydrocarbon sensors based on a stabilized zirconia electrolyte and proton conductor-containing platinum electrode
SENSORS AND ACTUATORS B-CHEMICAL 81 (1): 55-63 DEC 2001
Times Cited: 24
Hibino T, Hashimoto A, Suzuki M, et al.
Proton conduction at the surface of Y-doped BaCeO3
JOURNAL OF PHYSICAL CHEMISTRY B 105 (46): 11399-11401 NOV 2001
Times Cited: 22
Hibino T, Hashimoto A, Inoue T, et al.
A solid oxide fuel cell using an exothermic reaction as the heat source
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 148 (6): A544-A549 JUN 2001
Times Cited: 72
Hibino T, Hashimoto A, Kakimoto S, et al.
Zirconia-based potentiometric sensors using metal oxide electrodes for detection of hydrocarbons
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 148 (1): H1-H5 JAN 2001
Times Cited: 63

2000

Hibino T, Hashimoto A, Inoue T, et al.
Single-chamber solid oxide fuel cells at intermediate temperatures with various hydrocarbon-air mixtures
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 147 (8): 2888-2892 AUG 2000
Times Cited: 79
Hibino T, Hashimoto A, Inoue T, et al.
A low-operating-temperature solid oxide fuel cell in hydrocarbon-air mixtures
SCIENCE 288 (5473): 2031-2033 JUN 16 2000
Times Cited: 560
Hibino T, Tsunekawa H, Tanimoto S, et al.
Improvement of a single-chamber solid-oxide fuel cell and evaluation of new cell designs
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 147 (4): 1338-1343 APR 2000
Times Cited: 57
Hibino T, Wang SQ, Kakimoto S, et al.
One-chamber solid oxide fuel cell constructed from a YSZ electrolyte with a Ni anode and LSM cathode
SOLID STATE IONICS 127 (1-2): 89-98 JAN 2000
Times Cited: 84
Hibino T, Inoue T, Sano M
Electrochemical reduction of NO by alternating current electrolysis using yttria-stabilized zirconia as the solid electrolyte Part Ⅱ. Modification of Pd electrode by coation with Rh
SOLID STATE IONICS 130 (1-2): 31-39 MAY 2000
Times Cited: 30
Hibino T, Inoue T, Sano M
Electrochemical reduction of NO by alternating current electrolysis using yttria-stabilized zirconia as the solid electrolyte Part I. Characterizations of alternating current electrolysis of NO
SOLID STATE IONICS 130 (1-2): 19-29 MAY 2000
Times Cited: 30

1999

Hibino T, Tanimoto S, Kakimoto S, et al.
High-temperature hydrocarbon sensors based on a stabilized zirconia electrolyte and metal oxide electrodes
ELECTROCHEMICAL AND SOLID STATE LETTERS 2 (12): 651-653 DEC 1999
Times Cited: 44
Hibino T, Kakimoto S, Sano M
Non-nernstian behavior at modified Au electrodes for hydrocarbon gas sensing
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 146 (9): 3361-3366 SEP 1999
Times Cited: 46
Hibino T, Kuwahara Y, Wang S
Effect of electrode and electrolyte modification on the performance of one-chamber solid oxide fuel cell
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 146 (8): 2821-2826 AUG 1999
Times Cited: 26
Hibino T, Wang SQ, Kakimoto S, et al.
Single chamber solid oxide fuel cell constructed from an yttria-stabilized zirconia electrolyte
ELECTROCHEMICAL AND SOLID STATE LETTERS 2 (7): 317-319 JUL 1999
Times Cited: 55

1998

Hibino T, Kuwahara Y, Wang SQ, et al.
Nonideal electromotive force of zirconia sensors for unsaturated hydrocarbon gases
ELECTROCHEMICAL AND SOLID STATE LETTERS 1 (4): 197-199 OCT 1998
Times Cited: 44
Hibino T, Wang SQ, Kakimoto S, et al.
Detection of propylene under oxidizing conditions using zirconia-based potentiometric sensor
SENSORS AND ACTUATORS B-CHEMICAL 50 (2): 149-155 JUL 1998
Times Cited: 32

1997

Hibino T, Ushiki K, Kuwahara Y
Electrochemical oxygen pump using CeO2-based solid electrolyte for NOx detection independent of O-2 concentration
SOLID STATE IONICS 93 (3-4): 309-314 JAN 1997
Times Cited: 23

1996

Hibino T, Suzuki K, Ushiki K, et al.
Ultra-fine grinding of La0.8Sr0.2MnO3 oxide by vibration mill
APPLIED CATALYSIS A-GENERAL 145 (1-2): 297-306 OCT 1996
Times Cited: 22
Hibino T, Ushiki K, Kuwahara Y
New concept for simplifying SOFC system
SOLID STATE IONICS 91 (1-2): 69-74 OCT 1996
Times Cited: 50
Hibino T, Ushiki K, Kuwahara Y, et al.
Electrochemical removal of NO in the presence of excess O2, H2O and CO2 using Sm2O3-doped CeO2 as a solid electrolyte
SOLID STATE IONICS 89 (1-2): 13-16 AUG 1996
Times Cited: 21

1995

Hibino T, Ushiki K, Sato T
A novel cell design for simplifying SOFC system
SOLID STATE IONICS 81 (1-2): 1-3 OCT 1995
Times Cited: 38
Asano K, Hibino T, Iwahara H
A novel solid oxide fuel-cell system using the partial oxidation of methane
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 142 (10): 3241-3245 OCT 1995
Times Cited: 61
Iwahara H, Mori T, Hibino T
Electrochemical studies on ionic-conduction in Ca-doped BaCeO3
SOLID STATE IONICS 79: 177-182 JUL 1995
Times Cited: 27
Hibino T, Ushiki K, Kuwahara Y, et al.
Medium-temperature electrolysis of NO and CH4 under lean-burn conditions using ytrria-stabilized zirconia as a solid-electrolyte
JOURNAL OF THE ELECTROCHEMICAL SOCIETY-FALADAY 91 (13): 1955-1959 JUL 1995
Times Cited: 22

1994

Hamakawa S, Hibino T, Iwahara H
Electrochemical hydrogen permeation in a proton-hole mixed conductor and its application to a membrane reactor
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 141 (7): 1720-1725 JUL 1994
Times Cited: 103
Hibino T
Electrochemical removal of NO and CH4 from oxidizing atmosphere
CHEMISTRY LETTERS (5): 927-930 MAY 1994
Times Cited: 47
Hibino T, Asano K, Iwahara H
Improvement of CAPCIUS cell using SrCe0.95Yb0.05O3-α as a solid electrolyte
CHEMISTRY LETTERS (3): 485-488 MAR 1994
Times Cited: 24
Hibino T, Hamakawa S, Suzuki T, et al.
Recycling of carbon dioxide using a proton conductor as a solid electrolyte
JOURNAL OF APPLIED ELECTROCHEMISTRY 24 (2): 126-130 FEB 1994
Times Cited: 31

1993

Hibino T, Akimoto T, Iwahara H, et al.
Protonic conduction of mordenite-type zeorite
SOLID STATE IONICS 67 (1-2): 71-76 DEC 1993
Times Cited: 22
Hibino T, Niwa M, Murakami Y
Inactivation of external surface of mordenite and ZSM-5 by chemical-vapor-deposition of silicon alkoxide
ZEOLITES 13 (7): 518-523 SEP-OCT 1993
Times Cited: 49
Hibino T, Mizutani K, Iwahara H
H/D isotope effect on electrochemical pumps of hydrogen and water-vapor using a proton-conductive solid-electrolyte
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 140 (9): 2588-2592 SEP 1993
Times Cited: 29
Hibino T, Iwahara H
Simplification of solid oxide fuel cell system using partial oxidation of methane
CHEMISTRY LETTERS (7): 1131-1134 JUL 1993
Times Cited: 87
Iwahara H, Yajima T,Hibino T, et al.
Performance of solid oxide fuel cell using proton and oxide ion mixed conductors based on BaCe1-XSmXO3-α
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 140 (6): 1687-1691 JUN 1993
Times Cited: 222
Iwahara H, Yajima T, Hibino T, et al.
Protonic conduction in calcium, strontium and barium zirconates
SOLID STATE IONICS 61 (1-3): 65-69 MAY 1993
Times Cited: 377
Hibino T, Iwahara H
CO2 sensors using BaCeO3-based ceramics
SENSORS AND ACTUATORS B-CHEMICAL 13 (1-3): 483-485 MAY 1993
Times Cited: 22
Hamakawa S,Hibino T, Iwahara H
Electrochemical methane coupling using protonic conductors
JOURNAL OF THE ELECTROCHEMICAL SOCIETY 140 (2): 459-462 FEB 1993
Times Cited: 91

1992

Hibino T, Mizutani K, Yajima T, et al.
Characterization of proton in Y-doped SrZrO3 polycrystal by IR spectroscopy
SOLID STATE IONICS 58 (1-2): 85-88 NOV 1992
Times Cited: 43
Hibino T, Mizutani K, Yajima T, et al.
Evaluation of proton conductivity in SrCeO3, BaCeO3, CaZrO3 AND SrZrO3 by temperature programmed desorption method
SOLID STATE IONICS 57 (3-4): 303-306 OCT 1992
Times Cited: 95

1991

Hibino T, Niwa M, Murakami Y
Shape-selectivity over HZSM-5 modified by chemical vapor-deposition of silicon alkoxide
JOURNAL OF CATALYSIS 128 (2): 551-558 APR 1991
Times Cited: 140

1989

Niwa M, Hibino T, Murata H, et al.
A silica monolayer on alumina and evidence of lack of acidity of silanol attached to alumina
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (5): 289-290 MAR 1 1989
Times Cited: 27

1988

Niwa M, Kawashima Y, Hibino T, et al.
Mechanism of chemical vapor-deposition of silicon alkoxide on mordenites
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 1 84: 4327-4336 Part 12 1988
Times Cited: 26
TOP